Issue 32, 2024

Alignment transport between ultracold polar molecules

Abstract

We propose an array of ultracold polar molecules as a platform to study alignment transport between molecules. We envision a polar molecule being aligned with an intense off-resonant laser field whose alignment migrates to a nearby molecule due to dipole–dipole interactions. Our results show that the transport of the alignment is due to a complex interplay between electric field-driven excitations and dipole–dipole interactions. All mechanisms for alignment transfer are elucidated and analyzed. Using NaCs as a prototype molecule, we find that the time for alignment transfer is O(10 μs), which makes the phenomena readily observable in the lab.

Graphical abstract: Alignment transport between ultracold polar molecules

Article information

Article type
Paper
Submitted
11 May 2024
Accepted
06 Jul 2024
First published
08 Jul 2024

Phys. Chem. Chem. Phys., 2024,26, 21513-21519

Alignment transport between ultracold polar molecules

J. Smucker and J. Pérez-Ríos, Phys. Chem. Chem. Phys., 2024, 26, 21513 DOI: 10.1039/D4CP01956C

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