Issue 17, 2024
From the journal:

CrystEngComm

Orthogonal stimulation of structural transformations in photo-responsive MOF films through linker functionalization†

Sumea Klokic, ORCID logo ab   Benedetta Marmiroli,b   Denys Naumenko,b   Giovanni Birarda, ORCID logo c   Simone Dal Zilio, ORCID logo d   Miriam de J. Velásquez-Hernández, ORCID logo e   Paolo Falcaro, ORCID logo e   Lisa Vaccari ORCID logo c  and  Heinz Amenitsch ORCID logo *b  

* Corresponding authors

a CERIC-ERIC, Elettra Sincrotrone Trieste – SAXS Beamline, S.S. 14, 163.5 km, Basovizza, Trieste 34149, Italy

b Institute of Inorganic Chemistry, Graz University of Technology, 8010 Graz, Austria
E-mail: heinz.amentisch@tugraz.at

c Elettra Sincrotrone Trieste – SISSI Bio Beamline, S.S. 14, 163.5 km, Basovizza, Trieste 34149, Italy

d IOM-CNR, Laboratorio TASC, S.S. 14, 163.5 km, Basovizza, Trieste 34149, Italy

e Institute of Physical and Theoretical Chemistry, Graz University of Technology, 8010 Graz, Austria

Abstract

Controlling the magnitude of structural dynamics in flexible MOF films by an applied stimulus is largely desired for specific applications such as energy storage. Herein, by introducing chlorine substituents in an azobenzene-infiltrated Cl-DMOF-1 film structure, a significantly slowed structural response is obtained upon photo-switching of the system.

Graphical abstract: Orthogonal stimulation of structural transformations in photo-responsive MOF films through linker functionalization

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Article information

DOI
https://doi.org/10.1039/D4CE00221K
Article type
Communication
Submitted
07 Mar 2024
Accepted
11 Mar 2024
First published
22 Mar 2024
This article is Open Access
Creative Commons BY-NC license

CrystEngComm, 2024,26, 2228-2232

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Orthogonal stimulation of structural transformations in photo-responsive MOF films through linker functionalization

S. Klokic, B. Marmiroli, D. Naumenko, G. Birarda, S. Dal Zilio, M. D. J. Velásquez-Hernández, P. Falcaro, L. Vaccari and H. Amenitsch, CrystEngComm, 2024, 26, 2228 DOI: 10.1039/D4CE00221K

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