Issue 94, 2024
From the journal:

Chemical Communications

Synthesis of environmentally friendly energetic cocrystal derived from commodity chemicals†

Kazuki Inoue,a   Yosuke Nishiwaki,b   Mieko Kumasaki, ORCID logo *c   Shinya Matsumotoc  and  Ken Okadad  

* Corresponding authors

a Graduate School of Environment and Information Sciences, Yokohama National University, 79-7 Tokiwadai, Hodogaya-ku, Yokohama, Kanagawa, Japan

b National Institute of Occupational Safety and Health, Japan, 1-4-6 Umezono, Kiyose, Tokyo, Japan

c Faculty of Environment and Information Sciences, Yokohama National University, 79-7 Tokiwadai, Hodogaya-ku, Yokohama, Kanagawa, Japan
E-mail: kumasaki@ynu.ac.jp

d Research Institute of Science for Safety and Sustainability, National Institute of Advanced Industrial Science and Technology (AIST), AIST Tsukuba Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki, Japan

Abstract

Ammonium nitrate (AN) is a green oxidizer in the field of energetic materials. However, hygroscopicity and phase transitions have prevented AN from being put into practical use. To address these two drawbacks, a cocrystallization technique was applied to AN in this study. An AN/glycine (Gly) cocrystal was newly prepared and characterized; both AN/Gly and AN/sarcosine exhibited decreased hygroscopicity and did not exhibit a phase transition.

Graphical abstract: Synthesis of environmentally friendly energetic cocrystal derived from commodity chemicals

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Article information

DOI
https://doi.org/10.1039/D4CC04037F
Article type
Communication
Submitted
08 Aug 2024
Accepted
31 Oct 2024
First published
06 Nov 2024
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2024,60, 13963-13966

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Synthesis of environmentally friendly energetic cocrystal derived from commodity chemicals

K. Inoue, Y. Nishiwaki, M. Kumasaki, S. Matsumoto and K. Okada, Chem. Commun., 2024, 60, 13963 DOI: 10.1039/D4CC04037F

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