Modulating the guest binding ability within mixed-coordination geometry [Pd(μ-L)4RuCl2]2+ and [Pd(μ-L)4Pt]4+ cage architectures

Hayden B. Gearing; Tilo Söhnel; Paul Young; Lynn Lisboa; L. James Wright; James D. Crowley; Christian G. Hartinger

doi:10.1039/D4CC03613A

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Modulating the guest binding ability within mixed-coordination geometry [Pd(μ-L)₄RuCl₂]²⁺ and [Pd(μ-L)₄Pt]⁴⁺ cage architectures†

Hayden B. Gearing,^a Tilo Söhnel,

^ab Paul Young,

^c Lynn Lisboa,^d L. James Wright,

^a James D. Crowley

^bd and Christian G. Hartinger

*^a

Author affiliations

* Corresponding authors

^a School of Chemical Sciences, University of Auckland, Private Bag 92019, Auckland 1142, New Zealand
E-mail: c.hartinger@auckland.ac.nz

^b MacDiarmid Institute for Advanced Materials and Nanotechnology, Victoria University of Wellington, PO Box 600, Wellington 6140, New Zealand

^c School of Biological Sciences, University of Auckland, Private Bag 92019, Auckland 1142, New Zealand

^d Department of Chemistry, University of Otago, PO Box 56, Dunedin 9054, New Zealand

Abstract

Heterobimetallic cages built from Pd and either octahedral Ru or square-planar Pt moieties and bridged by ligands with H bonding-accepting or -donating properties are reported. They showed stimulus-responsive dis- and reassembly, while guest binding was found to be dependent on the complementary properties of the guest to the host in terms of charge, size and H bonding properties.

This article is part of the themed collection: ChemComm 60th Anniversary Collection

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/D4CC03613A
Article type: Communication
Submitted: 19 Jul 2024
Accepted: 30 Aug 2024
First published: 30 Aug 2024

Download Citation

Chem. Commun., 2024,60, 10950-10953

Permissions

Request permissions

Modulating the guest binding ability within mixed-coordination geometry [Pd(μ-L)₄RuCl₂]²⁺ and [Pd(μ-L)₄Pt]⁴⁺ cage architectures

H. B. Gearing, T. Söhnel, P. Young, L. Lisboa, L. J. Wright, J. D. Crowley and C. G. Hartinger, Chem. Commun., 2024, 60, 10950 DOI: 10.1039/D4CC03613A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications