Copper(I)-catalyzed (4+3)-cycloaddition of 4-indolylcarbinols with aziridines has been accomplished to furnish azepinoindoles. The chirality transfer, substrate scope, functional group tolerance, natural product modification and tandem C–C/C–N bond formation are the important practical features.
S. Kar, P. K. Maharana, S. Maity, V. Trivedi and T. Punniyamurthy, Chem. Commun., 2024, 60, 12008 DOI: 10.1039/D4CC03544E
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