Harnessing reductive BF2-complexation via Ru(ii)-catalyzed N–O cleavage of isoxazoles

Abstract

Developed here is a highly fluorescent organic N,O bidentate BF₂ complex from isoxazole in the presence of a Ru(II) catalyst. Herein, the complexation proceeds via a selective N–O cleavage of the isoxazole ring. The complex shows absorption (λ_max,abs) in the range of 352–363 nm with an extinction coefficient (ε) in the range of 8000–64 000 M⁻¹ cm⁻¹, and fluorescence emission (λ_max,em) in the range of 413–485 nm with a Stokes shift of 61–125 nm having quantum yield up to 33%. Apart from the solution state, the solid BF₂ complex 2u exhibits absorption at 405 nm and strong fluorescence emission at 550 nm with a quantum yield of 26.9%.