Diamidopyridine-supported titanium dibenzyl complexes undergo coordination-induced C-C reductive elimination upon addition of alkynes and concomitant formation of titanacyclopentadienes. The distinct radical mechanism of this reductive mechanism gives new insights into C-C bond formation with titanium.
P. Fritsche, L. Geyer, C. Czernetzki and G. Hierlmeier, Chem. Commun., 2024, Accepted Manuscript , DOI: 10.1039/D4CC02500H
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