Issue 68, 2024
From the journal:

Chemical Communications

Coordination-induced reductive elimination from a titanium(iv) complex†

Paul Fritsche,‡a   Lucia Geyer,‡a   Corinna Czernetzki ORCID logo a  and  Gabriele Hierlmeier ORCID logo *a  

* Corresponding authors

a Julius-Maximilians-Universität Würzburg, Institut für Anorganische Chemie, Am Hubland, 97074 Würzburg, Germany
E-mail: gabriele.hierlmeier@uni-wuerzburg.de

Abstract

Diamidopyridine-supported titanium dibenzyl complexes undergo coordination-induced C–C reductive elimination upon addition of alkynes and quantitative formation of titanacyclopentadienes. The distinct radical mechanism of this reductive mechanism gives new insights into C–C bond formation with titanium.

Graphical abstract: Coordination-induced reductive elimination from a titanium(iv) complex

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Article information

DOI
https://doi.org/10.1039/D4CC02500H
Article type
Communication
Submitted
23 May 2024
Accepted
14 Jul 2024
First published
15 Jul 2024

Chem. Commun., 2024,60, 9030-9033

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Coordination-induced reductive elimination from a titanium(IV) complex

P. Fritsche, L. Geyer, C. Czernetzki and G. Hierlmeier, Chem. Commun., 2024, 60, 9030 DOI: 10.1039/D4CC02500H

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