Here, we develop a new absorbent for efficient separation of cyclohexanol (CHA-ol) and cyclohexene (CHA-ene) by using crystals of pillar[6]arene with three benzoquinone units (P3QA). P3QA crystals are found to show remarkable selectivity for CHA-ol in 50:50 (v/v) CHA-ol:CHA-ene mixtures with a purity of 95.2%, along with vapochromic behavior.
R. Liu, M. Li, Z. Liu and B. Hua, Chem. Commun., 2024, Accepted Manuscript , DOI: 10.1039/D4CC02407A
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