From the journal:

Chemical Communications

In situ confinement of ultra-small metal nanoparticles in redox-active zirconium MOFs for catalysis†

Fugang Li,‡a   Jinyi Huang,‡a   Yuxuan Meng,a   Ji Li,b   Liangliang Zhang ORCID logo *ab  and  Daopeng Sheng*c  

* Corresponding authors

a Fujian Cross Strait Institute of Flexible Electronics (Future Technologies), Fujian Normal University, Fuzhou 350117, China
E-mail: ifellzhang@fjnu.edu.cn

b Institute of Flexible Electronics, Northwestern Polytechnical University (NPU), Xi'an 710072, China

c State Key Laboratory of Radiation Medicine and Protection, School for Radiological and Interdisciplinary Sciences (RAD-X) and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions, Soochow University, Suzhou, China

Abstract

Herein, we successfully fabricated ultra-small metal nanoparticles into two stable Zr-based metal–organic frameworks via in situ redox reactions between triphenylamine and the corresponding metal ions to afford Pd NPs@1 and Pd NPs@2, which exhibit excellent activity and reusability for Suzuki coupling reactions as heterogeneous catalysts.

Graphical abstract: In situ confinement of ultra-small metal nanoparticles in redox-active zirconium MOFs for catalysis

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Article information

DOI
https://doi.org/10.1039/D4CC01976H
Article type
Communication
Submitted
25 Apr 2024
Accepted
18 Jul 2024
First published
18 Jul 2024

Chem. Commun., 2024, Advance Article

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In situ confinement of ultra-small metal nanoparticles in redox-active zirconium MOFs for catalysis

F. Li, J. Huang, Y. Meng, J. Li, L. Zhang and D. Sheng, Chem. Commun., 2024, Advance Article , DOI: 10.1039/D4CC01976H

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