CsAlB3O6Cl: the rational construction of a KBBF-type structure with aligned 2∞[AlB3O6Cl] layers via introducing unprecedented [AlO3Cl] tetrahedra

Haoran Liu; Jiahao Jiao; Abudukadi Tudi; Qingyu Liu; Zhihua Yang; Shilie Pan; Min Zhang

doi:10.1039/D4CC01827C

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

CsAlB₃O₆Cl: the rational construction of a KBBF-type structure with aligned ²_∞[AlB₃O₆Cl] layers via introducing unprecedented [AlO₃Cl] tetrahedra†

Haoran Liu,‡^ab Jiahao Jiao,

‡^ab Abudukadi Tudi,

^ab Qingyu Liu,^ab Zhihua Yang,

^ab Shilie Pan

*^ab and Min Zhang

*^ab

Author affiliations

* Corresponding authors

^a Research Center for Crystal Materials, State Key Laboratory of Functional Materials and Devices for Special Environmental Conditions, Xinjiang Key Laboratory of Functional Crystal Materials, Xinjiang Technical Institute of Physics and Chemistry, CAS, 40-1 South Beijing Road, Urumqi 830011, China

^b Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

The first chloroaluminoborate, CsAlB₃O₆Cl, with innovative AlO₃Cl tetrahedra and a perfect planar arrangement of [B₃O₆] groups, was structurally designed and synthesized via chlorination of [AlO₄] tetrahedra. Simultaneously, the smooth introduction of the [AlO₃Cl] group into borates initiates the development of a chloroaluminoborate and greatly enriches the structural chemistry of aluminoborates.

This article is part of the themed collection: CC 60th Anniversary Authors Collection

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/D4CC01827C
Article type: Communication
Submitted: 18 Apr 2024
Accepted: 20 May 2024
First published: 23 May 2024

Download Citation

Chem. Commun., 2024, Advance Article

Permissions

Request permissions

CsAlB₃O₆Cl: the rational construction of a KBBF-type structure with aligned ²_∞[AlB₃O₆Cl] layers via introducing unprecedented [AlO₃Cl] tetrahedra

H. Liu, J. Jiao, A. Tudi, Q. Liu, Z. Yang, S. Pan and M. Zhang, Chem. Commun., 2024, Advance Article , DOI: 10.1039/D4CC01827C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Chemical Communications