Issue 50, 2024

Electronic interaction between dimethyl carbonate and Li+ studied by attenuated total reflectance far-ultraviolet spectroscopy

Abstract

Organic electrolytes with Li+ were analyzed by far-ultraviolet (≤200 nm) spectroscopy, achieved by an attenuated total reflectance setup. The spectra showed a redshift with Li+ addition, attributed to the charge transfer, as revealed by quantum chemical calculations. Multivariate analysis successfully decomposed the spectra into pure solvent and Li-coordinated solvent components.

Graphical abstract: Electronic interaction between dimethyl carbonate and Li+ studied by attenuated total reflectance far-ultraviolet spectroscopy

Supplementary files

Article information

Article type
Communication
Submitted
15 Apr 2024
Accepted
21 May 2024
First published
21 May 2024

Chem. Commun., 2024,60, 6375-6378

Electronic interaction between dimethyl carbonate and Li+ studied by attenuated total reflectance far-ultraviolet spectroscopy

H. Sato, N. Ueno and I. Tanabe, Chem. Commun., 2024, 60, 6375 DOI: 10.1039/D4CC01775G

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