Bottom-up synthesis of ion-pair-bridged metal–organic framework for H+ conduction

Keiichiro Maegawa; Hayata Okamoto; Kazuhiro Hikima; Go Kawamura; Atsushi Nagai; Atsunori Matsuda

doi:10.1039/D4CC01706D

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Bottom-up synthesis of ion-pair-bridged metal–organic framework for H⁺ conduction†

Keiichiro Maegawa,

*^ab Hayata Okamoto,^a Kazuhiro Hikima,

^a Go Kawamura,^a Atsushi Nagai

^b and Atsunori Matsuda

*^a

Author affiliations

* Corresponding authors

^a Department of Electrical and Electronic Information Engineering, Toyohashi University of Technology, 1-1 Hibarigaoka, Tempaku-cho, Toyohashi, Aichi 441-8580, Japan
E-mail: uwk96futeko@gmail.com, matsuda@ee.tut.ac.jp

^b Next-Generation Energy Systems group, Centre of Excellence ENSEMBLE3 sp. z o.o., Wolczynska 133, Warsaw 01-919, Poland

Abstract

As a novel conceptual synthesis of a metal–organic framework (MOF)-based proton conductor, UiO-66 based on a pyridinedicarboxylic acid phosphate (PyDC-PA) ion pair linker has been developed, in which the phosphoric acid is fixed to the N donor moiety of pyridine via an ionic bond.

Download options Please wait...

Supplementary files

Supplementary information PDF (631K)

Article information

DOI: https://doi.org/10.1039/D4CC01706D
Article type: Communication
Submitted: 11 Apr 2024
Accepted: 02 Jun 2024
First published: 05 Jun 2024

Download Citation

Chem. Commun., 2024,60, 6925-6928

Permissions

Request permissions

Bottom-up synthesis of ion-pair-bridged metal–organic framework for H⁺ conduction

K. Maegawa, H. Okamoto, K. Hikima, G. Kawamura, A. Nagai and A. Matsuda, Chem. Commun., 2024, 60, 6925 DOI: 10.1039/D4CC01706D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications