Issue 42, 2024

Triptycene-based diiron(ii) mesocates: spin-crossover in solution

Abstract

Triptycene-based diiron(II) and dizinc(II) mesocates were obtained using a novel rigid ligand with two pyridylbenzimidazole chelating units fused into the triptycene scaffold. Studies on the diiron(II) assembly in solution showed that the complex undergoes thermal-induced one-step spin-crossover with T1/2 at 243 K (Evans method).

Graphical abstract: Triptycene-based diiron(ii) mesocates: spin-crossover in solution

Supplementary files

Article information

Article type
Communication
Submitted
19 Feb 2024
Accepted
26 Apr 2024
First published
29 Apr 2024
This article is Open Access
Creative Commons BY license

Chem. Commun., 2024,60, 5522-5525

Triptycene-based diiron(II) mesocates: spin-crossover in solution

R. Mobili, G. Preda, D. Dondi, E. Monzani, D. Vadivel, C. Massera, D. Pasini and V. Amendola, Chem. Commun., 2024, 60, 5522 DOI: 10.1039/D4CC00812J

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