Issue 41, 2024

Visible light-promoted [3+2] cyclization reaction of vinyl azides with perfluoroalkyl-substituted-imidoyl sulfoxonium ylides

Abstract

Visible-light-induced [3+2] cyclization of vinyl azides with perfluoroalkyl-substituted imidoyl sulfoxonium ylides has been developed for the first time. In this transformation, perfluoroalkyl-substituted imidoyl sulfoxonium ylides are firstly employed as a carbon radical precursor under visible light irradiation, providing a new and efficient method for the construction of perfluoroalkyl-substituted 1-pyrrolines.

Graphical abstract: Visible light-promoted [3+2] cyclization reaction of vinyl azides with perfluoroalkyl-substituted-imidoyl sulfoxonium ylides

Supplementary files

Article information

Article type
Communication
Submitted
17 Feb 2024
Accepted
16 Apr 2024
First published
17 Apr 2024

Chem. Commun., 2024,60, 5407-5410

Visible light-promoted [3+2] cyclization reaction of vinyl azides with perfluoroalkyl-substituted-imidoyl sulfoxonium ylides

M. Yang, Y. Meng, H. Mehfooz and Y. Zhao, Chem. Commun., 2024, 60, 5407 DOI: 10.1039/D4CC00777H

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