Tailoring fluorescent ZIF-8 nanostructures through calix[4]pyrrole modification: tunable size and enhanced organic micropollutant removal capacity

Nida Ük; Fatma Yelda Ünlü; Özge İbiş; Ilgın Nar; Abdullah Aydogan; Caner Ünlü

doi:10.1039/D3CC05934K

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Tailoring fluorescent ZIF-8 nanostructures through calix[4]pyrrole modification: tunable size and enhanced organic micropollutant removal capacity†

Nida Ük,

^a Fatma Yelda Ünlü,

^b Özge İbiş,^b Ilgın Nar,

^c Abdullah Aydogan

*^b and Caner Ünlü

*^ab

Author affiliations

* Corresponding authors

^a Department of Polymer Science and Technology, Istanbul Technical University, Maslak, Istanbul, Turkey
E-mail: canerunlu@itu.edu.tr, aydoganab@itu.edu.tr

^b Department of Chemistry, Istanbul Technical University, Maslak, Istanbul, Turkey

^c Istanbul Technical University Nanotechnology Research and Application Center (ITUNano), Istanbul, Turkey

Abstract

Whitish-blue light emitting fluorescent ZIF-8 structures were synthesized by means of bis-carboxylate functional calix[4]pyrrole (BCCP) modification. The calix[4]pyrrole concentration was also manipulated to tune the sizes of the ZIF-8 structures. Moreover, the BCCP-modified ZIF-8 samples exhibited enhanced organic micropollutant removal capacity from aqueous solutions.

This article is part of the themed collection: Fundamental Processes in Optical Nanomaterials

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Article information

DOI: https://doi.org/10.1039/D3CC05934K
Article type: Communication
Submitted: 05 Dec 2023
Accepted: 15 Dec 2023
First published: 18 Dec 2023

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Chem. Commun., 2024,60, 866-869

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Tailoring fluorescent ZIF-8 nanostructures through calix[4]pyrrole modification: tunable size and enhanced organic micropollutant removal capacity

N. Ük, F. Y. Ünlü, Ö. İbiş, I. Nar, A. Aydogan and C. Ünlü, Chem. Commun., 2024, 60, 866 DOI: 10.1039/D3CC05934K

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Chemical Communications

Tailoring fluorescent ZIF-8 nanostructures through calix[4]pyrrole modification: tunable size and enhanced organic micropollutant removal capacity†

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Tailoring fluorescent ZIF-8 nanostructures through calix[4]pyrrole modification: tunable size and enhanced organic micropollutant removal capacity

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