This Feature Article overviews a new class of π-conjugated materials – macrocyclic furans. Starting from their synthesis, we review their unique structural, optical and electronic properties, chemical reactivity, and potential application as synthons. Finally, we discuss the study of oligofuran macrocycles as a model system for exploring the concept of global aromaticity and the size limitation of Hückel's rule in neutral macrocycles.
O. Dishi, Y. Rahav and O. Gidron, Chem. Commun., 2024, 60, 522 DOI: 10.1039/D3CC05225G
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