Issue 13, 2024

Modulation of circularly polarized luminescence by swelling of microgels functionalized with enantiopure [Ru(bpy)3]2+ luminophores

Abstract

Chemoresponsive microgels functionalized with enantiomeric Δ- or Λ-[Ru(bpy)3]2+ showed tunable chiroptical properties upon swelling and shrinking. The tuning is triggered by a modulation of the local mobility of [Ru(bpy)3]2+ upon addition of fructose, controlling interactions and distances between [Ru(bpy)3]2+ and phenylboronic acid.

Graphical abstract: Modulation of circularly polarized luminescence by swelling of microgels functionalized with enantiopure [Ru(bpy)3]2+ luminophores

Supplementary files

Article information

Article type
Communication
Submitted
05 Sep 2023
Accepted
20 Dec 2023
First published
21 Dec 2023

Chem. Commun., 2024,60, 1743-1746

Modulation of circularly polarized luminescence by swelling of microgels functionalized with enantiopure [Ru(bpy)3]2+ luminophores

K. Yoshida, M. Kajiwara, Y. Okazaki, L. Véronique, F. Zinna, N. Sojic, L. Bouffier, J. Lacour, V. Ravaine and R. Oda, Chem. Commun., 2024, 60, 1743 DOI: 10.1039/D3CC04391F

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