Highly selective detection of 2,4-dinitrophenol by fluorescent NH2-MIL-125(Ti) via dual-parameter sensing technology

Abstract

The organic contaminant 2,4-dinitrophenol (2,4-DNP) is widely prevalent and poses significant risks to human health. Although numerous in-depth studies having been reported on the highly sensitive detection of 2,4-DNP, there are still challenges to its selective detection. Here, the fluorescence intensity ratio (I₀/I) and emission peak shift (Δλ) were utilized for selective detection of 2,4-DNP by NH₂-MIL-125(Ti). Notably, the emission peak of the NH₂-MIL-125(Ti) suspension exhibited a remarkable red shift in the presence of 2,4-DNP (Δλ = 26 nm), accompanied by the blue shift or weak red shift of analogs, which provided a solid basis for selective detection of 2,4-DNP. Meanwhile, the I₀/I ratio of the NH₂-MIL-125(Ti) suspension exhibited a robust linear correlation with 2,4-DNP at the low concentration range (0–70 μM). The interaction of the analyte with NH₂-MIL-125(Ti) was revealed to involve intermolecular charge transfer (ICT) and fluorescence resonance energy transfer (FRET) through XPS, FTIR, and UV-vis absorption spectroscopy. Additionally, we achieved the detection of 2,4-DNP using a smartphone by recognizing both the blue (B) values and the luminance (L) values. The obtained results demonstrated that the NH₂-MIL-125(Ti) probe based on dual-parameter sensing technology exhibited excellent potential for selectively detecting 2,4-DNP in water environments, thereby offering significant prospects for its application in water quality assessment.