Issue 9, 2023

Colloidal synthesis of a heterostructured CuCo2S4/g-C3N4/In2S3 nanocomposite for photocatalytic hydrogen evolution

Abstract

The introduction of the hot injection approach in designing effective nanocomposites with heterostructures significantly enhances the photocatalytic performance by reinforcing their active sites and facilitating the directed transfer of photocarriers. Here, we present a rapid and easy fabrication process for the synthesis of CuCo2S4 and CuCo2S4/g-C3N4/In2S3 heterostructures by the colloidal hot injection method and employed them for photocatalytic H2 generation under visible light irradiation. The as-prepared materials exhibit unique properties, specifically visible light absorption, suppressed recombination of photogenerated charge carriers, and sustainable H2 production over prolonged exposure to light irradiation. The catalysts were characterized well to investigate the structural, photophysical and electronic properties. In the CuCo2S4/g-C3N4/In2S3 composite, CuCo2S4 and In2S3 nanoparticles are deposited on 2D g-C3N4. The post synthetically modified hybrid photocatalyst CuCo2S4/g-C3N4/In2S3 greatly influences the redox and e–h+ separation process and exhibits an impressive rate of HER (∼11.66 mmol h−1g−1), suppressing the pristine CuCo2S4 (∼1.32 mmol h−1g−1). Because of the band gap energy and potential of the conduction band of the components, we proposed a type-I scheme of photocatalytic reaction. The experimental results indicate that the heterostructured materials exhibit remarkably high activity for hydrogen evolution. The DFT results demonstrate the role of g-C3N4 and In2S3 in improving the photocatalytic performance of the hybrid CuCo2S4 catalyst, which leads to superior catalytic behaviour. Furthermore, the increased photocatalytic activity of CuCo2S4/g-C3N4/In2S3 is ascribed to the synergistic interaction of CuCo2S4, In2S3 nanoparticles and g-C3N4, which form an electron transfer channel to harvest photo-generated electrons.

Graphical abstract: Colloidal synthesis of a heterostructured CuCo2S4/g-C3N4/In2S3 nanocomposite for photocatalytic hydrogen evolution

Supplementary files

Article information

Article type
Paper
Submitted
02 May 2023
Accepted
09 Aug 2023
First published
09 Aug 2023
This article is Open Access
Creative Commons BY license

Energy Adv., 2023,2, 1512-1520

Colloidal synthesis of a heterostructured CuCo2S4/g-C3N4/In2S3 nanocomposite for photocatalytic hydrogen evolution

A. Gautam, S. Sk, A. Jamma, B. M. Abraham, M. Ahmadipour and U. Pal, Energy Adv., 2023, 2, 1512 DOI: 10.1039/D3YA00191A

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