Issue 6, 2023

Transient deformation and swelling of paper by aqueous co-solvent solutions

Abstract

Inkjet printing inks frequently contain polar liquids of low volatility such as glycerol or poly(ethylene glycols) in addition to the main solvent water. The deposition of these liquids on paper sheets induces swelling of the cellulose fibers, which leads to an overall, anisotropic deformation of the sheet. We characterized the corresponding strain components by means of a grid projection method and white light interferometry. For pure water, most of the hydroexpansion strain vanishes again after drying is complete. However, for aqueous solutions of non-volatile co-solvents, a large fraction of the deformation persists after the water has evaporated. Because swelling occurs only after liquid enters the cellulose fibers, monitoring the dynamics of expansion provides insight into the pore-fiber distribution of co-solvents. The corresponding timescales of pore-fiber transport strongly depend on the co-solvent concentration, as a sufficient quantity of water is needed to plasticize the fiber walls.

Graphical abstract: Transient deformation and swelling of paper by aqueous co-solvent solutions

Supplementary files

Article information

Article type
Paper
Submitted
20 Oct 2022
Accepted
13 Jan 2023
First published
16 Jan 2023
This article is Open Access
Creative Commons BY license

Soft Matter, 2023,19, 1202-1211

Transient deformation and swelling of paper by aqueous co-solvent solutions

C.-L. Wong, S. Wang, S. Karimnejad, M. G. Wijburg, H. Mansouri and A. A. Darhuber, Soft Matter, 2023, 19, 1202 DOI: 10.1039/D2SM01388F

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