Issue 19, 2023

Rational molecular and doping strategies to obtain organic polymers with ultralong RTP

Abstract

Organic-doped polymers and room-temperature phosphorescence (RTP) mechanisms have been widely reported. However, RTP lifetimes >3 s are rare and RTP-enhancing strategies are incompletely understood. Herein, we demonstrate a rational molecular doping strategy to obtain ultralong-lived, yet bright RTP polymers. The n–π* transitions of boron- and nitrogen-containing heterocyclic compounds can promote a triplet-state population, and the grafting of boronic acid onto polyvinyl alcohol can inhibit molecular thermal deactivation. However, excellent RTP properties were achieved by grafting 1–0.1% (N-phenylcarbazol-2-yl)-boronic acid rather than (2-/3-/4-(carbazol-9-yl)phenyl)boronic acids to afford record-breaking ultralong RTP lifetimes up to 3.517–4.444 s. These results showed that regulation of the interacting position between the dopant and matrix molecules to directly confine the triplet chromophore could more effectively stabilize triplet excitons, disclosing a rational molecular-doping strategy for achieving polymers with ultralong RTP. Based on the energy-donor function of blue RTP, an ultralong red fluorescent afterglow was demonstrated by co-doping with an organic dye.

Graphical abstract: Rational molecular and doping strategies to obtain organic polymers with ultralong RTP

Supplementary files

Article information

Article type
Edge Article
Submitted
09 Mar 2023
Accepted
17 Apr 2023
First published
19 Apr 2023
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY-NC license

Chem. Sci., 2023,14, 5177-5181

Rational molecular and doping strategies to obtain organic polymers with ultralong RTP

Y. Zhang, S. Zhang, G. Liu, Q. Sun, S. Xue and W. Yang, Chem. Sci., 2023, 14, 5177 DOI: 10.1039/D3SC01276J

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