A rare isocyanide derived from an unprecedented neutral yttrium(ii) bis(amide) complex

Abstract

A room temperature stable complex formulated as Y(NHAr*)₂ has been prepared, where Ar* = 2,6-(2,4,6-(ⁱPr)₃C₆H₂)C₆H₃, by KC₈ reduction of ClY(NHAr*)₂. Based on EPR evidence, Y(NHAr*)₂ is an example of a d¹ Y(II) complex with significant delocalization of the unpaired electron density from the metal to the ligand. The isolation of molecular divalent metal complexes is challenging for rare earth elements such as yttrium. In fact, stabilization of the divalent state requires judicious ligand design that allows the metal center to be coordinatively saturated. Divalent rare earth elements tend to be reactive towards various substrates. Interestingly, Y(NHAr*)₂ reacts as a radical donor towards ^tBuNC to generate an unusual yttrium isocyanide complex, CNY(NHAr*)₂, based on spectroscopic evidence and single-crystal X-ray diffraction data.