Highly dispersive PEI-modified CDs@ZIF-L dual-emitting fluorescent sensor for detecting metal ions

Abstract

The leaf-like zeolitic imidazolate framework (ZIF-L) is a promising porous nanomaterial that has attracted increasing attention as an ideal host material to encapsulate functional fluorescent nanoparticles for designing fluorescent sensors. However, owing to the large particle size, gravity readily facilitates the precipitation of the ZIF-L from the aqueous solution, and thus lead to imperfect experimental results. Herein, we report a simple and rapid synthetic method which uses the polyethyleneimine (PEI)-modified ZIF-L as a host to solve the precipitation problem and construct a dual-emitting system that combines its fluorescence with carbon dots (CDs). Furthermore, CDs@ZIF-L/PEI with dual-emitting centres could be utilised as a ratio fluorescence sensor to detect Hg²⁺ ions. The sensor exhibited excellent dispersibility and good selectivity for sensing Hg²⁺ ions, with a limit of detection (LOD) of 14.5 nM. Furthermore, experimental results reveal that the CDs@ZIF-L/PEI fluorescent sensor could be effectively dispersed into agarose and less polar organic solvents such as DMF, MeOH, EtOH and CH₃CN, expanding the application scope of the fluorescent sensor.