Type-II ternary Bi2WO6/rGO/SnFe2O4 heterojunction nanocomposites and their photocatalytic efficiency towards 4-nitrophenol reduction

Abstract

In this study, tin ferrite (SnFe₂O₄-spinel) and bismuth tungstate (Bi₂WO₆) encapsulated on reduced graphene oxide (rGO) were synthesised using the hydrothermal method. This heterostructure nanocomposite was characterised using Fourier transform infrared spectroscopy (FT-IR), Ultraviolet-visible spectroscopy (UV-Vis), powder X-ray diffraction (XRD), Scanning electron microscopy (SEM), FT-Raman Spectroscopy (FT-Raman) and X-ray photoelectron spectroscopy (XPS) methods. The powder XRD results showed an increase in lattice parameters and a decrease in size when SnFe₂O₄ and Bi₂WO₆ were encapsulated on rGO. The catalytic activity of the type-II ternary Bi₂WO₆/rGO/SnFe₂O₄ heterojunction nanocomposite was checked using a model reduction reaction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) in the presence of NaBH₄ as the reducing agent under light exposure. Bi₂WO₆/rGO/SnFe₂O₄ showed better catalytic efficiency than the individual components like SnFe₂O₄, rGO/SnFe₂O₄, Bi₂WO₆, rGO/Bi₂WO₆ and Bi₂WO₆/SnFe₂O₄ nanocomposites. Thus, the type-II ternary Bi₂WO₆/rGO/SnFe₂O₄ heterojunction nanocatalyst with better surface area and lower surface energy could be considered as a promising UV-light sensitive catalyst for the detoxification of various environmental pollutants and for other environmental remediations.