Synthesis of Sb2S3 nanosphere layer by chemical bath deposition for the photocatalytic degradation of methylene blue dye

Abstract

An antimony tri-sulfide Sb₂S₃ nanosphere photocatalyst was effectively deposited utilizing sodium thiosulfate and antimony chloride as the starting precursors in a chemical bath deposition process. This approach is appropriate for the large-area depositions of Sb₂S₃ at low deposition temperatures without the sulfurization process since it is based on the hydrolytic decomposition of starting compounds in aqueous solution. X-ray diffraction patterns and Raman spectroscopy analysis revealed the formation of amorphous Sb₂S₃ layers. The scanning electron microscopy images revealed that the deposited Sb₂S₃ has integrated small nanospheres into sub-microspheres with a significant surface area, resulting in increased photocatalytic activity. The optical direct bandgap of the Sb₂S₃ layer was estimated to be about 2.53 eV, making amorphous Sb₂S₃ appropriate for the photodegradation of organic pollutants in the presence of solar light. The possibility of using the prepared Sb₂S₃ layer in the photodegradation of methylene blue aqueous solutions was investigated. The degradation of methylene blue dye was performed to evaluate the photocatalytic property of Sb₂S₃ under visible light. The amorphous Sb₂S₃ exhibited photocatalytic activity for the decolorization of methylene blue solution under visible light. The mechanism for the photocatalytic degradation of methylene blue has been proposed. Our results suggest that the amorphous Sb₂S₃ nanospheres are valuable material for addressing environmental remediation issues.