La2CoO4+δ perovskite-mediated peroxymonosulfate activation for the efficient degradation of bisphenol A

Abstract

Sulfate radical-based technology has been considered as an efficient technology to remove pharmaceuticals and personal care products (PPCPs) with heterogeneous metal-mediated catalysts for the activation of peroxymonosulfate (PMS). In this study, La₂CoO_4+δ perovskite with Ruddlesden–Popper type structure was synthesised by the sol–gel method, which was employed in PMS activation. Different characteriazation technologies were applied for the characterization of La₂CoO_4+δ, such as SEM-EDX, XRD, and XPS technologies. A common organic compound, bisphenol A (BPA), is used as a target contaminant, and the effect impactors were fully investigated and explained. The results showed that when the dosage of La₂CoO_4+δ was 0.5 g L⁻¹ and the concentration of PMS was 1.0 mM in neutral pH solution, about 91.1% degradation efficiency was achieved within 25 minutes. Quenching experiments were introduced in the system to verify the catalytic mechanism of PMS for the BPA degradation, proving the existence of superoxide, hydroxyl radicals and sulfate radicals, which are responsible for the catalytic degradation of BPA. Moreover, the reusability and stability of the catalyst were also conducted which showed good stability during the reaction. This work would improve the applications of A₂BO₄-type perovskites for activating PMS to degrade BPA.