Benz[e]indenyl and benz[f]indenyl molybdenum compounds: evidence of the η3-coordination mode

Jiří Štěpán; Jaromír Vinklárek; Ivana Císařová; Libor Dostál; Jan Honzíček

doi:10.1039/D3NJ04406H

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Benz[e]indenyl and benz[f]indenyl molybdenum compounds: evidence of the η³-coordination mode†

Jiří Štěpán,^a Jaromír Vinklárek,

^a Ivana Císařová,^b Libor Dostál

^a and Jan Honzíček

*^c

Author affiliations

* Corresponding authors

^a Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentská 573, 532 10 Pardubice, Czech Republic

^b Department of Inorganic Chemistry, Faculty of Science, Charles University in Prague, Hlavova 2030/8, 128 43 Prague 2, Czech Republic

^c Institute of Chemistry and Technology of Macromolecular Materials, Faculty of Chemical Technology, University of Pardubice, Studentská 573, 532 10 Pardubice, Czech Republic
E-mail: jan.honzicek@upce.cz

Abstract

This study reports the synthesis and characterization of new molybdenum compounds bearing benz[e]indenyl and benz[f]indenyl ligands. The capability of the ligands to undergo η⁵-to-η³ haptotropic rearrangement was evidenced on reactions with tris(pyrazolyl)methane. Appearance of the η³-coordination mode was determined by NMR spectroscopy and X-ray structure analysis on a single crystal.

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Article information

DOI: https://doi.org/10.1039/D3NJ04406H
Article type: Paper
Submitted: 20 Sep 2023
Accepted: 30 Oct 2023
First published: 30 Oct 2023
This article is Open Access

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New J. Chem., 2023,47, 21396-21403

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Benz[e]indenyl and benz[f]indenyl molybdenum compounds: evidence of the η³-coordination mode

J. Štěpán, J. Vinklárek, I. Císařová, L. Dostál and J. Honzíček, New J. Chem., 2023, 47, 21396 DOI: 10.1039/D3NJ04406H

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