Issue 17, 2023

Bright lead-free Cs3Cu2I5 perovskite scintillators for thermal neutron detection

Abstract

All-inorganic lead-free perovskite scintillators have attracted wide applications in X-ray imaging recently due to their low cost, high resolution, and environmental friendliness. However, their potential application in thermal neutron detection has yet to be thoroughly explored. In this article, the properties of all-inorganic perovskite Cs3Cu2I5 scintillators for thermal neutron detection have been investigated. A simple synthesis process has been applied to produce Cs3Cu2I5 scintillators. The as-prepared Cs3Cu2I5 crystals exhibit intense blue emission with a photoluminescence quantum yield (PLQY) of 60.3%. A composite of 6LiF, Cs3Cu2I5, and poly(methyl methacrylate) (PMMA) has been utilized for thermal neutron detection, which has a light yield of about 28 000 photons per thermal neutron, four times that of a commercial 6Li-glass (GS20) scintillator (7000 photons per thermal neutron). Effective neutron-gamma-pulse-discrimination has been achieved using a network-dynamics digital filter, effectively separating thermal neutrons from gamma events. Our composite scintillators have a high thermal neutron absorption efficiency of about 60%. In addition, Cs3Cu2I5 crystals are more sensitive to X-ray irradiation compared to commercial Na-doped CsI scintillators. Our work provides a new strategy for large-scale perovskite-based thermal neutron detection and imaging.

Graphical abstract: Bright lead-free Cs3Cu2I5 perovskite scintillators for thermal neutron detection

Supplementary files

Article information

Article type
Paper
Submitted
29 May 2023
Accepted
15 Jun 2023
First published
21 Jun 2023
This article is Open Access
Creative Commons BY-NC license

Mater. Adv., 2023,4, 3714-3723

Bright lead-free Cs3Cu2I5 perovskite scintillators for thermal neutron detection

L. Yao, W. Gui, X. Zhou, C. Li, S. Zhang, J. K. Zhao and C. L. Wang, Mater. Adv., 2023, 4, 3714 DOI: 10.1039/D3MA00270E

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements