One-step synthesis of a ZIF-8/90-based type I porous liquid

Jingqiu Hu; Zhaofang Liu; Shuangyin Tang; Meng Yao; Dezhen Zhang; Mifen Cui; Dong Yang; Jihai Tang; Xu Qiao; Zhuxiu Zhang

doi:10.1039/D3DT02423G

One-step synthesis of a ZIF-8/90-based type I porous liquid†

Jingqiu Hu,^a Zhaofang Liu,^a Shuangyin Tang,^a Meng Yao,^a Dezhen Zhang,^a Mifen Cui,^a Dong Yang,^a Jihai Tang,*^ab Xu Qiao^ab and Zhuxiu Zhang

*^a

Author affiliations

* Corresponding authors

^a State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, No. 30 Puzhunan Road, Nanjing 211816, China

^b Jiangsu National Synergetic Innovation Centre for Advanced Materials (SICAM), No. 5 Xinmofan Road, Nanjing 210009, China
E-mail: jhtang@njtech.edu.cn, qct@njtech.edu.cn, zhuxiu.zhang@njtech.edu.cn

Abstract

A Type I porous liquid based on the mixed-linker zeolitic imidazolate framework, ZIF-8/90-PL, has been prepared by a one-step imine condensation reaction and characterized by X-ray diffraction, FT-IR spectroscopy, TGA and rheology analysis. This facile preparation strategy of a porous liquid has enormous industrial production and application potential, with over one kilogram of ZIF-8/90-PL being successfully prepared. ZIF-8/90-PL can be directly used as a liquid absorbent or be co-processed with alumina hollow fibers to form a composite membrane with improved selectivity in the context of CO₂ separation from CH₄ or N₂. This simple synthesis method is expected to be extended to other metal–organic frameworks.

Dalton Transactions

One-step synthesis of a ZIF-8/90-based type I porous liquid†

Abstract

Supplementary files

Article information

Download Citation

Permissions

One-step synthesis of a ZIF-8/90-based type I porous liquid

Social activity

Search articles by author

Spotlight

Advertisements