Porous nanosheet–nanosphere@nanosheet FeNi2-LDH@FeNi2S4 core–shell heterostructures for asymmetric supercapacitors
Abstract
Transition bimetallic sulphides have emerged as important electrode materials for supercapacitors owing to their low toxicity, environmental friendliness, cost-effectiveness, multiple oxidation states, high natural abundance, flexible structure, and high theoretical specific capacitance. Herein, a porous nanosheet–nanosphere@nanosheet FeNi2-LDH@FeNi2S4 (FNLDH@FNS) core–shell heterostructure was directly prepared on nickel foam (NF) via a two-step hydrothermal method. The prepared electrode material exhibits an outstanding electrochemical performance. The specific capacity (Cs) values are 806 and 450 C g−1 at current density (Dc) values of 1 and 6 A g−1, respectively, revealing a satisfactory magnification performance. In addition, the FNLDH@FNS electrode exhibits a long cycle life with an supercapacitor (SC) retention rate of 92.3% after 5000 cycles at a Dc of 6 A g−1. The FNLDH@FNS//activated carbon (AC) asymmetric SC assembled with FNLDH@FNS (positive electrode) and activated carbon (AC, negative electrode) displays an energy density (Ed) of 36.67 Wh kg−1 and a power density (Pd) of 775.17 W kg−1.