Issue 28, 2023
From the journal:

Dalton Transactions

Examining the reactivity of tris(ortho-carboranyl)borane with Lewis bases and application in frustrated Lewis pair Si–H bond cleavage†

Kanika Vashisth,a   Sanjay Dutta,a   Manjur O. Akrama  and  Caleb D. Martin ORCID logo *a  

* Corresponding authors

a Department of Chemistry and Biochemistry, Baylor University, One Bear Place #97348, Waco, Texas 76798, USA
E-mail: caleb_d_martin@baylor.edu

Abstract

Reactions of tris(ortho-carboranyl)borane with Lewis bases reveals only small bases bind. The tremendous bulk and Lewis acidity is leveraged in frustrated Lewis pair Si–H cleavage with a wider range of Lewis bases and greater efficacy than B(C6F5)3.

Graphical abstract: Examining the reactivity of tris(ortho-carboranyl)borane with Lewis bases and application in frustrated Lewis pair Si–H bond cleavage

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Article information

DOI
https://doi.org/10.1039/D3DT01557B
Article type
Paper
Submitted
23 May 2023
Accepted
21 Jun 2023
First published
21 Jun 2023

Dalton Trans., 2023,52, 9639-9645

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Examining the reactivity of tris(ortho-carboranyl)borane with Lewis bases and application in frustrated Lewis pair Si–H bond cleavage

K. Vashisth, S. Dutta, M. O. Akram and C. D. Martin, Dalton Trans., 2023, 52, 9639 DOI: 10.1039/D3DT01557B

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