On the mercuration, palladation, transmetalation and direct auration of a C^N^C pincer ligand

Abstract

The C^N^C ligand 2,6-bis(2,3-dialkoxyphenyl)pyridine forms dimercury and orthopalladated complexes, both of which may be transmetallated to gold(III) complexes; the gold complexes may also be formed directly in a Rh(III)-catalysed process, hence it is possible to circumvent the use of organomercury intermediates in the synthesis of this important class of compound.