Halogen engineering of organic–inorganic hybrid perovskites displaying nonlinear optical, fluorescence properties and phase transition

Abstract

In order to meet the needs of social development, increasing research attention has been paid to multifunctional molecular-based phase-transition materials. The traditional phase-transition materials with a single functional property can be transformed into magnificent ones by adding additional functional properties—for instance photoluminescence and magnetic order— because having two or more functional properties simultaneously greatly broadens the fields of their applications. At present, there are very few multifunctional phase-transition materials showing excellent performance, and the crystal structure design and performance optimization of materials still need to be studied in depth. Herein, we report the development of two organic–inorganic hybrid materials: (MBA)₂ZnI₄ (1, MBA = 4-methoxybenzylammonium) with switchable dielectricity and a high phase-transition temperature (T_c = 359.55 K), and (MBA)₂ZnBr₄ (2) with green luminescence (λ_exc = 314 nm) and nonlinear optical properties (0.75× KDP). A two-dimensional (2D) fingerprint analysis of the Hirshfeld surface plots revealed a significant difference between the hydrogen-bonding interaction before the phase transition and that afterwards. The two compounds were further verified, from energy band structure calculations, to be direct-band-gap semiconductors. In conclusion, this work has provided a viable strategy, involving the application of chemical modifications, for designing various functional materials.