Probing borafluorene B–C bond insertion with gold acetylide and azide

Yijie Li; Yu-Hsuan Shen; Alec M. Esper; John R. Tidwell; Adam S. Veige; Caleb D. Martin

doi:10.1039/D2DT03672J

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Probing borafluorene B–C bond insertion with gold acetylide and azide†

Yijie Li,

^a Yu-Hsuan Shen,

^b Alec M. Esper,

^b John R. Tidwell,

^a Adam S. Veige

*^b and Caleb D. Martin

*^a

Author affiliations

* Corresponding authors

^a Baylor University, Department of Chemistry and Biochemistry, One Bear Place #97348, Waco, TX 76798, USA
E-mail: caleb_d_martin@baylor.edu

^b University of Florida, Department of Chemistry, Center for Catalysis, Gainesville, FL 32611, USA

Abstract

The reaction of Ph₃PAuN₃ with 9-Ph-9-borafluorene resulted in complexation of the azide to boron while a gold acetylide reacted with 9-Ph-9-borafluorene to insert the acetylide carbon to access a six-membered boracycle with an exocyclic double bond.

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Article information

DOI: https://doi.org/10.1039/D2DT03672J
Article type: Paper
Submitted: 15 Nov 2022
Accepted: 09 Dec 2022
First published: 13 Dec 2022

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Dalton Trans., 2023,52, 668-674

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Probing borafluorene B–C bond insertion with gold acetylide and azide

Y. Li, Y. Shen, A. M. Esper, J. R. Tidwell, A. S. Veige and C. D. Martin, Dalton Trans., 2023, 52, 668 DOI: 10.1039/D2DT03672J

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Probing borafluorene B–C bond insertion with gold acetylide and azide†

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Probing borafluorene B–C bond insertion with gold acetylide and azide

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