Probing borafluorene B–C bond insertion with gold acetylide and azide†
Yijie
Li, 
a
Yu-Hsuan
Shen,
b
Alec M.
Esper,
b
John R.
Tidwell,
a
Adam S.
Veige
*b
and
Caleb D.
Martin
*a
a
Yu-Hsuan
Shen,
b
Alec M.
Esper,
b
John R.
Tidwell,
a
Adam S.
Veige
*b
and
Caleb D.
Martin
*a
Abstract
The reaction of Ph3PAuN3 with 9-Ph-9-borafluorene resulted in complexation of the azide to boron while a gold acetylide reacted with 9-Ph-9-borafluorene to insert the acetylide carbon to access a six-membered boracycle with an exocyclic double bond.
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