Light-modulated colour transformation in highly intertwined vertically growing silver tungstate tubes

Abstract

Achieving control over growth kinetics in chemical garden architectures is challenging due to the nonequilibrium conditions. In this study, we demonstrate the vertical growth of silver tungstate chemical garden tubes under both illuminated and dark conditions, a phenomenon not observed in a comparable silver-based system, specifically silver silicate, under light exposure. Physicochemical factors, viz. thermo chemical radius of the tungstate anion, its density-buoyancy relation, the osmotic pressure gradient, and the hydration enthalpy, contributed to the tube appearance in silver tungstate even in light. Tubes grown in light illumination were greyish black, while dark-grown tubes were creamy white, and both tubes appeared twisted and highly intertwined. The colour of the as obtained silver tungstate tubes could be transformed via exposure to light. In the presence of a strong oxidizing agent, the growing tubes retain the original creamy white colour even under illumination. Colour transformation in chemical garden tubes has not yet been observed, and this report could lead the way.