Enantioselective addition of an imide N–H bond to alkenes was realized by use of a cationic iridium catalyst. Bulky diphosphine ligands such as DTBM-segphos, DTBM-MeO-biphep, and DTBM-binap were indispensable for the reaction. A variety of styrene derivatives, allylsilanes, and norbornene were good substrates to give the corresponding chiral adducts with high enantioselectivity.
K. Yamakawa, K. Sakamoto and T. Nishimura, Chem. Commun., 2023, 59, 12871 DOI: 10.1039/D3CC04406H
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