Issue 76, 2023
From the journal:

Chemical Communications

Fast and reversible solvent-vapor-induced 1D to 2D transformation in emissive Ag(i)-organic networks†

Maxim I. Rogovoy,a   Mariana I. Rakhmanova,a   Evgeniy H. Sadykov,a   Gia M. Carignan, ORCID logo b   Irina Yu. Bagryanskaya,c   Jing Li ORCID logo *b  and  Alexander V. Artem’ev ORCID logo *a  

* Corresponding authors

a Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, 3, Acad. Lavrentiev Ave, Novosibirsk, Russia
E-mail: chemisufarm@yandex.ru

b Department of Chemistry and Chemical Biology, Rutgers University, Piscataway, New Jersey, USA
E-mail: jingli@rutgers.edu

c Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of Russian Academy of Sciences, 9, Acad. Lavrentiev Ave, Novosibirsk, Russia

Abstract

We report here an unprecedentedly fast and reversible transformation between 1D and 2D MOFs/CPs induced through organic solvent vapours. The transformations occur at room temperature in just 15–20 min, accompanied by a significant change in the observed phosphorescence. These findings provide a new insight into the design of luminescent networks with stimuli-switchable dimensionality.

Graphical abstract: Fast and reversible solvent-vapor-induced 1D to 2D transformation in emissive Ag(i)-organic networks

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Article information

DOI
https://doi.org/10.1039/D3CC03540A
Article type
Communication
Submitted
24 Jul 2023
Accepted
25 Aug 2023
First published
26 Aug 2023

Chem. Commun., 2023,59, 11413-11416

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Fast and reversible solvent-vapor-induced 1D to 2D transformation in emissive Ag(I)-organic networks

M. I. Rogovoy, M. I. Rakhmanova, E. H. Sadykov, G. M. Carignan, I. Yu. Bagryanskaya, J. Li and A. V. Artem’ev, Chem. Commun., 2023, 59, 11413 DOI: 10.1039/D3CC03540A

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