Issue 76, 2023
From the journal:

Chemical Communications

A 3D tetrathiafulvalene-based metal–organic framework with intramolecular charge transfer for efficient near-infrared photothermal conversion†

Yu Zhang,‡ab   Zi-Wei Xia,‡a   Liang-jun Shen,ac   Hao Tang,ac   Xu-Feng Luo, ORCID logo *a   Xing Li ORCID logo *b  and  Xunwen Xiao ORCID logo *ac  

* Corresponding authors

a College of Material Science and Chemical Engineering, Ningbo University of Technology, 201 Fenghua Road, Ningbo, China
E-mail: luoxf@nbut.edu.cn, xunwenxiao@nbut.edu.cn

b School of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, China
E-mail: lixing@nbu.edu.cn

c Zhejiang Institute of Tianjin University, 201 Fenghua Road, Ningbo 315211, China

Abstract

The selection of metal centers can endow donor–metal–accepter (D–M–A) type MOFs with progressive framework dimensions. 3D Cd-based MOFs with intramolecular charge transfer caused by D–M–A exhibit a satisfactory photothermal conversion efficiency of 35.7%, with the temperature rapidly rising from 25 °C to 201 °C in 7 s under 808 nm laser irradiation.

Graphical abstract: A 3D tetrathiafulvalene-based metal–organic framework with intramolecular charge transfer for efficient near-infrared photothermal conversion

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Article information

DOI
https://doi.org/10.1039/D3CC03165A
Article type
Communication
Submitted
30 Jun 2023
Accepted
29 Aug 2023
First published
30 Aug 2023

Chem. Commun., 2023,59, 11429-11432

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A 3D tetrathiafulvalene-based metal–organic framework with intramolecular charge transfer for efficient near-infrared photothermal conversion

Y. Zhang, Z. Xia, L. Shen, H. Tang, X. Luo, X. Li and X. Xiao, Chem. Commun., 2023, 59, 11429 DOI: 10.1039/D3CC03165A

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