Issue 65, 2023

Calcium-stabilised transition metal bis(formyl) complexes: structure and bonding

Abstract

Reaction of a molecular calcium hydride with a series of group 9 dicarbonyl complexes [M(η5-C5Me5)(CO)2] (M = Co, Rh, Ir) led to the formation of both mono(formyl) and bis(formyl) complexes. The bis(formyl) complexes are unique. They have been characterised by multinuclear NMR spectroscopy and examples have been crystallographically characterised for the first time.

Graphical abstract: Calcium-stabilised transition metal bis(formyl) complexes: structure and bonding

Supplementary files

Article information

Article type
Communication
Submitted
23 Jun 2023
Accepted
11 Jul 2023
First published
11 Jul 2023
This article is Open Access
Creative Commons BY license

Chem. Commun., 2023,59, 9840-9843

Calcium-stabilised transition metal bis(formyl) complexes: structure and bonding

J. M. Parr, A. J. P. White and M. R. Crimmin, Chem. Commun., 2023, 59, 9840 DOI: 10.1039/D3CC03009A

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