A heteroleptic fused bi-cuboctahedral Cu21S2 cluster

Rhone P. Brocha Silalahi; Tzu-Hao Chiu; Hao Liang; Samia Kahlal; Jean-Yves Saillard; C. W. Liu

doi:10.1039/D3CC02936K

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A heteroleptic fused bi-cuboctahedral Cu₂₁S₂ cluster†

Rhone P. Brocha Silalahi,^a Tzu-Hao Chiu,^a Hao Liang,^b Samia Kahlal,^b Jean-Yves Saillard

*^b and C. W. Liu

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, National Dong Hwa University, No. 1, Sec. 2, Da Hsueh Rd. Shoufeng, Hualien 97401, Taiwan, Republic of China
E-mail: chenwei@gms.ndhu.edu.tw

^b Univ Rennes, CNRS, ISCR-UMR 6226, Rennes F-35000, France

Abstract

A new dicationic cluster, [Cu₂₁S₂{S₂CNⁿBu₂}₉(C₂Ph)₆]²⁺, where the Cu₂₁S₂ kernel consists of two S@Cu₁₂ cuboctahedra sharing a triangular Cu₃ face is reported. Its waist part is bridged by three dithiocarbamate ligands, each in a hexaconnective, hexametallic (μ₃, μ₃) coordination pattern, an unprecedented feature in Cu nanocluster chemistry.

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Article information

DOI: https://doi.org/10.1039/D3CC02936K
Article type: Communication
Submitted: 19 Jun 2023
Accepted: 11 Jul 2023
First published: 11 Jul 2023

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Chem. Commun., 2023,59, 9638-9641

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A heteroleptic fused bi-cuboctahedral Cu₂₁S₂ cluster

R. P. B. Silalahi, T. Chiu, H. Liang, S. Kahlal, J. Saillard and C. W. Liu, Chem. Commun., 2023, 59, 9638 DOI: 10.1039/D3CC02936K

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