Selective synthesis of boron-substituted enynes via a one-pot diboration/protodeboration sequence†
Abstract
An efficient and facile one-pot protocol to access enynylboronates via a Pt-catalyzed diboration/protodeboration strategy has been developed. The reaction is suitable for various silylsubstituted symmetrical and unsymmetrical 1,3-diynes, leading to π-conjugated organoboron compounds with excellent regio- and stereoselectivity.