Alberto M. Tous-Granados and Arturo J. Hernandez-Maldonado
Chem. Commun., 2023,59, 10020-10023
DOI:
10.1039/D3CC02683C,
Communication
The first example of a metalloligand(ML)-based non-interpenetrated SIFSIX MOF [Cu(ML)2(SiF6)]n (ML = Cu(pyac)2 = bis[3-(4-pyridyl)pentane-2,4-dionato]copper(II)) exhibits one-dimensional pore channels decorated with accessible Cu2+ sites that provide superior water vapor stability and CO2 selectivity over CH4vs. similar materials constructed from non-metal containing organic ligands.
