Issue 60, 2023
From the journal:

Chemical Communications

N-Fluorobenzenesulfonimide (NFSI) analogs with deprotectable substituents: synthesis of β-fluoroamines via catalytic aminofluorination of styrenes†

Yuki Ito,a   Akiya Adachi,a   Kohsuke Aikawa, ORCID logo *a   Kyoko Nozaki ORCID logo b  and  Takashi Okazoeac  

* Corresponding authors

a Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 2-11-16 Yayoi, Bunkyo-ku, Tokyo 113-8656, Japan
E-mail: aikawa@g.ecc.u-tokyo.ac.jp
Web: https://park.itc.u-tokyo.ac.jp/kawaguchi/index-en.html

b Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan

c Yokohama Technical Center, AGC Inc., 1-1 Suehiro-cho, Tsurumi-ku, Yokohama 230-0045, Japan

Abstract

The palladium-catalyzed aminofluorination of styrenes using novel N-fluorobenzenesulfonimide (NFSI) derivatives with deprotectable substituents, and the selective deprotection and transformation of the resulting products into amines under mild reaction conditions are herein disclosed.

Graphical abstract: N-Fluorobenzenesulfonimide (NFSI) analogs with deprotectable substituents: synthesis of β-fluoroamines via catalytic aminofluorination of styrenes

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Article information

DOI
https://doi.org/10.1039/D3CC02292G
Article type
Communication
Submitted
11 May 2023
Accepted
21 Jun 2023
First published
23 Jun 2023

Chem. Commun., 2023,59, 9195-9198

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N-Fluorobenzenesulfonimide (NFSI) analogs with deprotectable substituents: synthesis of β-fluoroamines via catalytic aminofluorination of styrenes

Y. Ito, A. Adachi, K. Aikawa, K. Nozaki and T. Okazoe, Chem. Commun., 2023, 59, 9195 DOI: 10.1039/D3CC02292G

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