Photochemical generation and reactivity of a new phthalocyanine-manganese–oxo intermediate

Tristan Skipworth; Seth Klaine; Rui Zhang

doi:10.1039/D3CC01275A

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Photochemical generation and reactivity of a new phthalocyanine-manganese–oxo intermediate†

Tristan Skipworth,^a Seth Klaine^a and Rui Zhang

*^a

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* Corresponding authors

^a Department of Chemistry, Western Kentucky University, 1906 College Heights Blvd., Bowling Green, Kentucky, USA
E-mail: rui.zhang@wku.edu
Fax: +1-270-7455631
Tel: +1-270-7453803

Abstract

The first phthalocyanine-manganese–oxo intermediate was successfully generated by visible-light photolysis of chlorate or nitrite manganese(III) precursors, and its reactivity towards organic substrates was kinetically probed and compared with other related porphyrin-metal–oxo intermediates.

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Article information

DOI: https://doi.org/10.1039/D3CC01275A
Article type: Communication
Submitted: 14 Mar 2023
Accepted: 28 Apr 2023
First published: 01 May 2023

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Chem. Commun., 2023,59, 6540-6543

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Photochemical generation and reactivity of a new phthalocyanine-manganese–oxo intermediate

T. Skipworth, S. Klaine and R. Zhang, Chem. Commun., 2023, 59, 6540 DOI: 10.1039/D3CC01275A

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Chemical Communications

Photochemical generation and reactivity of a new phthalocyanine-manganese–oxo intermediate†

Abstract

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Photochemical generation and reactivity of a new phthalocyanine-manganese–oxo intermediate

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