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Herein we report the self-assembly of an amino-acid substituted tetraphenylethylene (TPE) into a hydrogen-bonded dimeric capsule. Depending on the conditions applied the presented TPE derivative exhibits bluish photoluminescence with QYs up to 24% due to the AIE effect and excimer formation.

Graphical abstract: Self-assembly of a fluorescent hydrogen-bonded capsule based on an amino-acid functionalised tetraphenylethylene

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