An organocatalytic photoinduced 1,2-carbofunctionalization strategy for conjugated dienes has been developed. No exogenous photocatalyst or additives are required in this mild protocol and it allows for highly regioselective and efficient 1,2-carboisothiocyanation through the coupling of a diene, an alkyl radical and TMSNCS. The reaction is proposed to proceed through EDA complexation between the diene and TMSNCS.
A. Yadav, S. Sandha and C. B. Tripathi, Chem. Commun., 2023, 59, 5579 DOI: 10.1039/D3CC01121F
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