On the nucleation and fast reaction kinetics of 2D polymerisation with a 2-in-1 monomer

Niklas Herrmann; Cristina Martin; Samuel Eyley; Yusen Li; Nerea Bilbao; Víctor Rubio-Giménez; Mark Van der Auweraer; Wim Thielemans; Long Chen; Kunal S. Mali; Steven De Feyter

doi:10.1039/D3CC01032E

On the nucleation and fast reaction kinetics of 2D polymerisation with a 2-in-1 monomer†

Niklas Herrmann,

^a Cristina Martin,

^b Samuel Eyley,

^c Yusen Li,

^d Nerea Bilbao,^a Víctor Rubio-Giménez,

^e Mark Van der Auweraer,^a Wim Thielemans,

^c Long Chen,

*^d Kunal S. Mali

*^a and Steven De Feyter

*^a

Author affiliations

* Corresponding authors

^a Division of Molecular Imaging and Photonics, Department of Chemistry, KU Leuven, Celestijnenlaan 200F, 3001 Leuven, Belgium
E-mail: kunal.mali@kuleuven.be, steven.defeyter@kuleuven.be

^b Department of Physical Chemistry, Faculty of Pharmacy, University of Castilla-La Mancha, Albacete 02071, Spain

^c Sustainable Materials Lab, Department of Chemical Engineering, KU Leuven, Campus Kulak Kortrijk, Etienne Sabbelaan 53, 8500 Kortrijk, Belgium

^d State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, China
E-mail: longchen@jlu.edu.cn

^e Membrane Separations, Adsorption, Catalysis and Spectroscopy, Microbial and Molecular Systems, KU Leuven, 3001 Leuven, Belgium

Abstract

We report on the fast reaction kinetics of an imine based 2D polymer (2DP) formed from a single monomer carrying both aldehyde and amine groups. Our results point towards a direct monomer-to-crystalline polymer transition without an amorphous intermediate.

Chemical Communications

On the nucleation and fast reaction kinetics of 2D polymerisation with a 2-in-1 monomer†

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On the nucleation and fast reaction kinetics of 2D polymerisation with a 2-in-1 monomer

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