Issue 31, 2023

Double-resonance 17O NMR experiments reveal unique configurational information for surface organometallic complexes

Abstract

Obtaining three-dimensional (3D) configurational information of surface organometallic complexes is a persistent challenge due to the low spatial sensitivity of most spectroscopic methods. We show that employing 17O-enriched supports enables highly informative multidimensional NMR experiments, including radial and vertical distance measurements, that can be used to elucidate site geometry.

Graphical abstract: Double-resonance 17O NMR experiments reveal unique configurational information for surface organometallic complexes

Supplementary files

Article information

Article type
Communication
Submitted
27 Feb 2023
Accepted
21 Mar 2023
First published
21 Mar 2023
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2023,59, 4604-4607

Double-resonance 17O NMR experiments reveal unique configurational information for surface organometallic complexes

F. A. Perras, A. Arroyave, S. A. Southern, J. V. Lamb, Y. Li, A. LaPointe and M. Delferro, Chem. Commun., 2023, 59, 4604 DOI: 10.1039/D3CC00899A

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