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Abstract | Cited by

A versatile method for the chemical modification of a lithium-ion endohedral fullerene (Li+@C60) to connect various small molecules is described. The designed dieneazide linker enables the facile connection of Li+@C60 with small molecules bearing a terminal alkyne via Huisgen annulation and a subsequent Diels–Alder reaction. This strategy significantly expands the diversity of small molecules to be attached by Li+@C60.

Graphical abstract: Sequential click modification of a lithium-ion endohedral fullerene connecting small molecules through a dieneazide linker

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