Issue 35, 2023

Di-triazole boat conformation leads to metal–organic nanotube while chair conformation leads to coordination polymer

Abstract

Aliphatic-cored di-1,2,4-triazole ligands form both a metal–organic nanotube (MONT) and a coordination polymer upon reaction with silver nitrate. Control of the conformation of the cyclohexane ring between the triazoles determines the reaction outcome where a boat (formed from bicyclo[2.2.2]octane) yields a MONT while a chair (formed from cyclohexane) yields a coordination polymer.

Graphical abstract: Di-triazole boat conformation leads to metal–organic nanotube while chair conformation leads to coordination polymer

Supplementary files

Article information

Article type
Communication
Submitted
21 Aug 2023
Accepted
22 Aug 2023
First published
30 Aug 2023

CrystEngComm, 2023,25, 4929-4933

Author version available

Di-triazole boat conformation leads to metal–organic nanotube while chair conformation leads to coordination polymer

P. Nalaoh and D. M. Jenkins, CrystEngComm, 2023, 25, 4929 DOI: 10.1039/D3CE00835E

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